Product ID:N-3507 ORANGE TREE MARKING
MSDS Date:06/01/1990
FSC:8010
NIIN:01-274-7795
MSDS Number: BHXJM

NILES CHEMICAL PAINT CO.

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 616-683-3377

Info Phone: 219-236-5856

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 54%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 21%

COBALT (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

MANUFACTURER STATES UNIDENTIFIED INGREDIENTS ARE NOT

RTECS: 9999999ZZ

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRIT, LACRIMATION,
BLURRED VISION, VISUAL DISTURB & EYE BURNS. SKIN: CAN BE ABSORBED
IN TOXIC AMTS BY PROLONGED/REPEATED EXPOSURE. INHALED: NASAL &
RESPIRATORY IRRIT, CNS DEPRESSION, VER TIGO, UNCONSCIOUSNESS, EVEN
ASPHYXIATION. IF SWALLOWED: GASTROINTEST IRRITATION & ABDOMINAL
PAIN, BLINDNESS & EVEN DEATH
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA.
Effects of Overexposure:EYES: SEVERE IRRITATION, REDNESS, BLURRED
VISION, VISUAL DISTURB, EYE BURNS. SKIN: HARMFUL IF ABSORBED.
INHALED: DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, CONFUSION,
NAUSEA, HEADACHE, VERTIGO, UNCONSC IOUSNESS, EVEN ASPHYXIATION.
SWALLOWED:GASTROINTESTINAL IRRITATION, ABDOMINAL PAIN, NAUSEA,
VOMITING & DIARRHEA.
Medical Cond Aggravated by Exposure:NONE KNOWN. TARGET ORGANS: SKIN,
EYES, RESPIRATORY SYSTEM, CNS AND GI TRACT.

First Aid:INHALE: MOVE TO FRESH AIR IMMED. IF BREATHING STOP, GIVE CPR.
GET MED ATTN IMMED. SKIN: WASH WITH SOAP & WATER. EYES: FLUSH WITH
LARGE AMOUNTS OF WATER, AT LEAST 15 MIN, LIFTING LIDS. GET MED ATTN
IMM ED. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH THIS MATERIAL.
SWALLOW: DRINK 1 OR 2 GLASSES WATER. DO NOT INDUCE VOMIT. CONSULT
PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY.

Flash Point Method:TCC
Flash Point:85 F/29 C
Lower Limits:0.8
Upper Limits:36
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE-POSITIVE PRESS MODE
& FULL PROTECT CLOTHES. USE WTR TO COOL CLOSED CONTAINER, PREVENT
PRESS BUILD-UP/AUTO-IGNITE/EXPLOSION FROM HEAT
Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS, ELEC EQUIP, OPEN FLAME. CLOSED MAY EXPLODE FROM
EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES *

Spill Release Procedures:SMALL SPILL:ELIM ALL IGNITE SOURCES. AVOID
BREATHING VAPORS/SKIN CONTACT. USE INERT ABSORB(CLAY,SOIL)SHOVEL
RECLAIMED LIQ/ABSORB INTO RECOVERY/SALVAGE DRUMS. LARGE SPILL:SAME
AS ABOVE. ALSO DIKE TO PR EVENT FURTHER MOVEMENT, RECLAIM INTO
DRUMS/DISPOSE

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.

Respiratory Protection:WEAR APPROPRIATE(TY TC-23C-75)PROPERLY FITTED
HALF-MASK OR FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER
APPLICATION UNLESS AIR MONITOR DEMONSTRATES VAPOR/MIST LEVEL BELOW
APPLICABLE LIMITS.FO LLOW RESPIRATOR MFR'S DIRECTIONS FOR USE
Ventilation:VENT IN VOL/PATTERN TO KEEP AIR CONCENTRATE BELOW CURRENT
APPLICABLE OSHA PEL/TLV LIMIT & REMOVE DECOMP PRODUCTS FORMED
Protective Gloves:CHEMICAL RESISTANT (NITRILE OR VITON)
Eye Protection:CHEM GOGGLES/SAFETY GLASSES/FACE SHIELDS
Other Protective Equipment:WEAR CHEMICAL RESISTANT (NITRILE OR VITON)
CLOTHING AS NEEDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
RESTROOMS.
Supplemental Safety and Health
EMPLOYEES SHOULD WASH PROMPTLY WHEN SKIN BECOMES CONTAMINATED. REMOVE
ANY CLOTHING THAT BECOMES WET (TO AVOID FLAMMABILITY HAZARD) AND
WASH BEFORE REUSE.

Boiling Pt:B.P. Text:146 TO 330F
Decomp Temp:Decomp Text:N/E
Vapor Density:> THAN AIR
Viscosity:19 Z#2
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Percent Volatiles by Volume:70.26

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMP, SHOCK FROM DROPPING. (THIS
MATERIAL HAS BEEN FOUND TO BE STABLE UNDER REASONABLE CONDITIONS OF
STORAGE & USE)
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.